Synthesis and Structure of Tris (trialkylstannyl)??and Tris (dialkylhalostannyl) amines; Stabilization of the Sn3N Skeleton by Intramolecular Sn–X–Sn Bridges

A Appel, C Kober, C Neumann, H Nöth…

Index: Gasparis-Ebeling, Theo; Noeth, Heinrich Chemische Berichte, 1990 , vol. 123, p. 261 - 270

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Citation Number: 14

Abstract

Abstract Tris (triorganylstannyl) amines (R 2 R'Sn) 3 N (1, 2) with substituents R= R'= Me, Bu or R= Me and R'= iPr, tBu are obtained by metathesis from R 2 R'SnX and NaNH 2 in liquid ammonia or by transamination of R 3 SnNMe 2 with NH 3. Tris (diorga-nylhalostannyl)