Synthesis and reactions of tricyclo [5.2. 1.02, 6] dec-2 (6)-ene

N Takaishi, H Takahashi, O Yamashita…

Index: Takaishi, Naotake; Takahashi, Hitoshi; Yamashita, Osamu; Inamoto, Yoshiaki Journal of Organic Chemistry, 1986 , vol. 51, # 25 p. 4862 - 4865

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Citation Number: 5

Abstract

M 1 2 been focused on the pyramidalization of these olefin^,^,^ which possess tricycl0 [5.2. 1.0~~~] dec-2 (6)-ene (5) carbon skeleton as a partial framework. Recently, the synthesis of 5 was independently achieved by Bartlett8 and US.^ It is particularly interesting to compare the chemical behavior of 5 in comparison with that of 1 and 2. We now provide details of the preparation as well as some reactions of the olefin 5.