Iridium??Catalyzed Asymmetric Allylic Amination with Polar Amines: Access to Building Blocks with Lead??Like Molecular Properties

P Tosatti, J Horn, AJ Campbell, D House…

Index: Advanced Synthesis and Catalysis, , vol. 352, # 18 p. 3153 - 3157

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Citation Number: 28

Abstract

... Issue. Advanced Synthesis & Catalysis. ... allylic compounds; allylic substitution; asymmetric catalysis; iridium; lead-like compounds. ... The combination of an air-stable iridium catalyst and the dipolar aprotic solvent dimethyl sulfoxide (DMSO) allowed, for the first time, the systematic ...