Fused pyridazines: rigid multidentates for designing and fine-tuning the structure of hybrid organic/inorganic frameworks

…, J Sieler, H Krautscheid, KV Domasevitch

Index: Solntsev, Pavlo V.; Sieler, Joachim; Krautscheid, Harald; Domasevitch, Konstantin V. Dalton Transactions, 2004 , # 8 p. 1153 - 1158

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Citation Number: 12

Abstract

Fused pyridazines (1, 2, 3, 6, 7, 8-hexahydro-cinnolino [5, 4, 3-cde] cinnoline, L and its 2, 2, 7, 7-tetramethyl derivative, Me4L) are designed as rigid multidentate ligands for the construction of framework solids. In combination with copper (I) bromide (iodide) they provide excellent structural examples for predictive engineering and the possibilities for further fine-tuning of the framework architectures facilitated by the tetradentate function of ...