Palladium (II) complexes with salicylideneimine based tridentate ligand and triphenylphosphine: Synthesis, structure and catalytic activity in Suzuki–Miyaura cross …

…, BFT Cooper, CLB Macdonald, R Karvembu

Index: Muthu Tamizh, Manoharan; Cooper, Benjamin F.T.; MacDonald, Charles L.B.; Karvembu, Ramasamy Inorganica Chimica Acta, 2013 , vol. 394, p. 391 - 400

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Citation Number: 17

Abstract

Square planar palladium (II) complexes of the type [Pd (L)(PPh3)](1–6)(where L is the dianion of N-(2-mercaptophenyl) salicylideneimine or 5-substituted-N-(2-mercaptophenyl) salicylideneimine or N-(2-mercaptophenyl) naphthylideneimine) have been synthesised from the reactions between [Pd (PPh3) 4] and H2L in dichloromethane–ethanol mixture. The new complexes have been characterized by analytical and spectral (electronic, IR, 1H, ...