Nucleophilic Substitution at an Acetylenic Carbon

SI Miller, CE Orzech, CA Welch…

Index: Miller,S.I. et al. Journal of the American Chemical Society, 1962 , vol. 84, p. 2020 - 2021

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Citation Number: 25

Abstract

It was found recently that neutron activation could be used as a method for the preparationj3 from “cold” selenium-containing organic compounds, of the corresponding substances labeled with selenium-75; under these conditions only negligible decomposition occurred. It was of interest, therefore, to determine whether neutron activation could be applied to the phosphorus of nucleotides. Samples (100 to 200 mg.) of 5 '-adenosine monophosphate ( ...

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Pyrolysis of α-acyl, α,-thio phosphoranes→ thioacetylenes

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