Comparison of the supramolecular structures of two glyco lipids with chiral and nonchiral methyl-branched alkyl chains from natural sources

G Milkereit, VM Garamus, J Yamashita…

Index: Milkereit, Goetz; Garamus, Vasil M.; Yamashita, Jun; Hato, Masakatsu; Morr, Michael; Vill, Volkmar Journal of Physical Chemistry B, 2005 , vol. 109, # 4 p. 1599 - 1608

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Citation Number: 11

Abstract

Two alkyl glycosides with the same type of disaccharide headgroups (melibiose) and different methyl-branched alkyl chains, short chiral [(2 R, 4 R, 6 R, 8 R)-2, 4, 6, 8- tetramethyldecyl, extracted from an animal source] and long nonchiral (3, 7, 11, 15- tetramethylhexadecyl, from a plant source), were synthesized. The supramolecular aggregate structure formed in dilute solutions was investigated by small-angle neutron ...