Synthesis, crystal structures, and solid state quadratic nonlinear optical properties of a series of stilbazolium cations combined with gold cyanide counter-ion

…, S Bonhommeau, V Rodriguez, K Nakatani

Index: Lacroix, Pascal G.; Munoz, M. Carmen; Gaspar, Ana Belen; Real, Jose Antonio; Bonhommeau, Sebastien; Rodriguez, Vincent; Nakatani, Keitaro Journal of Materials Chemistry, 2011 , vol. 21, # 40 p. 15940 - 15949

Full Text: HTML

Citation Number: 11

Abstract

Three salts built up from (E)-4′-(dimethylamino)-stilbazolium (DMAS) H+,(E)-4′- (diethylamino)-stilbazolium (DEAS) H+,(E)-4′-{2-(methoxymethyl) pyrrolidinyl}-stilbazolium (MPS) H+, and gold cyanide as a counter-ion, are reported. The crystal structures have been solved for (DEAS) H+ Au (CN) 2−(Cc space group), and for (MPS) H+ Au (CN) 2−(P1 space group). The semi-empirical (ZINDO) calculated static hyperpolarizability (β0) of (MPS) H+ ...