The title compound, 6-C-glucopyranosyl-7-O-methylapigenin dihydrate, C22H22O10· 2H2O, is a natural C-glucosylflavone. The flavone skeleton is almost planar, the dihedral angle between the pyran moiety and the 4-hydroxyphenyl ring being 9.8 (3)°. The basal plane of the pyranosyl ring of the glucose moiety is almost perpendicular to the benzopyran ring system. The flavone skeletons are stacked along the a axis, forming layers parallel to (001 ...