Inorganic Chemistry

Preparation of bis (trifluoromethyl) tellurium, bis (trifluoromethyl) selenium, bis (trifluoromethyl) diselenium, tris (trifluoromethyl) antimony, tris (trifluoromethyl) arsine, …

EA Ganja, CD Ontiveros, JA Morrison

Index: Ganja, Edward A.; Ontiveros, Cynthia D.; Morrison, John A. Inorganic Chemistry, 1988 , vol. 27, p. 4535 - 4538

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Citation Number: 35

Abstract

The reactions between Hg (CF,), and representative halides of the lower elements of main groups 5 (15) and 6A (16) have been investigated. At 155 OC the reaction between TeBr, and Hg (CF3) 2 affords Te (CF3) 2 in 92% yield. In 4.5 h at 210 OC SeBr, and Hg (CF,), form Se (CF,), and Se,(CF,), in 67% and 3% yields, respectively; in 2.5 h at 170 OC they generate Se (CF,) 2 and Se2 (CF3)* in 26% and 57% yields, respectively. At 165 OC SbI, and Hg ( ...