. alpha.-Nitro sulfones

N Kornblum, MM Kestner, SD Boyd…

Index: Kornblum,N. et al. Journal of the American Chemical Society, 1973 , vol. 95, p. 3356 - 3361

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Citation Number: 29

Abstract

Abstract: Pure a-nitro sulfones (I) are readily obtained in 85-95 yields by treating a-iodo nitroparaffins with the salts of sulfinic acids. Inasmuch as the requisite a-iodonitro compounds are rapidly and quantitatively prepared from nitroparaffins, the overall result is a facile synthesis of a-nitro sulfones. When a-bromo nitroparaffins, a-chloro nitroparaffins, and a, a-dinitro compounds react with sulfinate salts, a-nitro sulfones (I) are again produced. ...