Catalyzed oxidative nitration of nitronate salts

L Garver, V Grakauskas, K Baum

Index: Garver, Lee C.; Grakauskas, V.; Baum, Kurt Journal of Organic Chemistry, 1985 , vol. 50, # 10 p. 1699 - 1702

Full Text: HTML

Citation Number: 46

Abstract

The oxidative cyanation and oxidative sulfonation of nitronate salts using ferricyanide as the oxidant has been rep~ rted.~?~ The use of sodium persulfate with a catalytic amount of ferricyanide was also found to be beneficial for these reactions, and the results are summarized in Table 11. The previously reported4 products were obtained from 2- nitropropane and nitrocyclohexane. The oxidative sulfonation of 2-nitro esters provides ...