The Journal of Organic Chemistry

The acyl effect on intramolecular palladium-catalyzed trimethylenemethane cycloadditions

BM Trost, TA Grese

Index: Journal of Organic Chemistry, , vol. 57, # 2 p. 686 - 697

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Citation Number: 36

Abstract

... Furthermore, the acyl-TMM chemistry permits incorporation of a bridgehead methyl substituent-the first example of a TMM-PdL2 cycloaddition in synthetically useful yields initiated by attack of a tertiary carbon in the first step to give a quaternary center. ... 690 J. Org. Chem., Vol. ...