Journal of Fluorine Chemistry

N-Fluoro-bis [(trifluoromethyl) sulfonyl] imide: interesting reactions involving nucleophilic attack on sulfonyl groups

W Ying, DD DesMarteau, ZQ Xu, M Witz

Index: Ying, Weiwen; Desmarteau, Darryl D.; Xu, Ze-Qi; Witz, Michael Journal of Fluorine Chemistry, 2000 , vol. 102, # 1-2 p. 135 - 139

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Citation Number: 12

Abstract

N-Fluoro-bis [(trifluoromethyl) sulfonyl] imide (1) undergoes reaction with a variety of nucleophiles to give a number of interesting products. Under suitable conditions, the sulfonyl group on 1 is subject to nucleophilic attack forming N-fluoro-trifluoromethylsulfonyl amide (3) and Nu-SO2CF3. Surprisingly, 3 can also function as a weak nucleophile in the absence of other stronger bases.