A bromine-catalysed free-radical oxidation of acetamides from primary and secondary alkylamines by H2O2

HR Bjørsvik, F Fontana, L Liguori…

Index: Bjorsvik; Fontana; Liguori; Minisci Chemical Communications, 2001 , # 6 p. 523 - 524

Full Text: HTML

Citation Number: 8

Abstract

New procedures based on the oxidation by bromine-catalysed hydrogen peroxide in a two- phase system provide simple and cheap transformations of alkylamines to carbonyl derivatives (aldehydes, ketones, carboxylic acid, imides, lactams) through the corresponding acetamides.