Photolysis of organopolysilanes. Novel addition reaction of aryl substituted disilanes to olefins

M Ishikawa, T Fuchikami, T Sugaya…

Index: Ishikawa,M. et al. Journal of the American Chemical Society, 1975 , vol. 97, p. 5923 - 5924

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Citation Number: 68

Abstract

Photolysis of p-tolylpentamethyldisilane (6) in the presence of isobutylene afforded crucial evidence for the migration of the trimethylsilyl group from silicon to the ortho carbon in the aromatic ring. Thus 2-trimethylsilyl-4-methylisobutyldimethylsilylbenzene (7)'O was obtained in 58% yield as a single product.

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