Gold??Catalysed Oxyarylation of Styrenes and Mono??and gem??Disubstituted Olefins Facilitated by an Iodine (III) Oxidant

…, GC Lloyd??Jones, CA Russell

Index: Ball, Liam T.; Lloyd-Jones, Guy C.; Russell, Christopher A. Chemistry - A European Journal, 2012 , vol. 18, # 10 p. 2931 - 2937

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Citation Number: 39

Abstract

Abstract 1-Hydroxy-1, 2-benziodoxol-3 (1H)-one (IBA) is an efficient terminal oxidant for gold- catalysed, three-component oxyarylation reactions. The use of this iodine (III) reagent expands the scope of oxyarylation to include styrenes and gem-disubstituted olefins, substrates that are incompatible with the previously reported Selectfluor-based methodology. Diverse arylsilane coupling partners can be employed, and in ...