Journal of Fluorine Chemistry

Development of (2-bromo-1, 1, 2, 2-tetrafluoroethyl)(phenyl) sulfane as tetrafluoroethyl-radical and tetrafluoroethylene-diradical synthons for additions to alkenes

Y Chernykh, P Beier

Index: US2002/86131 A1, ;

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Citation Number: 7

Abstract

PhSCF2CF2Br in the presence of tributyltin hydride and substochiometric triethylborane in dichloromethane underwent radical addition to alkenes to give the brom.