Rhodium (I)-centered cyclotriveratrylene

…, JNH Reek, JM Ernsting, P Van Leeuwen…

Index: Coolen, H. K. A. C.; Reek, J. N. H.; Ernsting, J. M.; Leeuwen, P. W. N. M. van; Nolte, R. J. M. Recueil des Travaux Chimiques des Pays-Bas, 1995 , vol. 114, # 9/10 p. 381 - 386

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Abstract

Abstract. The rigid bowl-shaped molecule cyclotriveratrylene (CTV, 1) was provided with short and long spacer arms terminating in triphenyl phosphite functions. These CTV ligands were used to immobilize a rhodium (I)-carbonyl-hydride complex. The ligand with short spacers gave a rigid, strained complex with a trigonal-coordination sphere around the rhodium. The ligand with long flexible spacers allowed the formation of a large cavity after ...

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