Syntheses and structures of (N′, N′-dimethylhydrazido) silanes

I Gronde, B Neumann, A Willner, T Pape…

Index: Gronde, Ingo; Neumann, Beate; Willner, Alexander; Pape, Tania; Mitzel, Norbert W. Dalton Transactions, 2009 , # 27 p. 5300 - 5309

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Abstract

The hydrazidosilanes Ph2Si (NHNMe2) 2 (1), Me2Si (NHNMe2) 2 (2), PhSi (NHNMe2) 3 (3), MeSi (NHNMe2) 3 (4), PhClSi (NHNMe2) 2 (5), MeClSi (NHNMe2) 2 (6), Me2ClSi (NHNMe2)(7), MeClHSi (NHNMe2)(8), MeHSi (NHNMe2) 2 (9), Me2HSi (NHNMe2)(10), Me2NN [HSi (NHNMe2) 2] 2 (11) and Si (NHNMe2) 4 (12) have been prepared by the reaction of the corresponding chlorosilanes with N, N-dimethylhydrazine. Some of the ...