Syntheses and coordination chemistry of aminomethylphosphine derivatives of adenine

…, G Hua, P Bhattacharyya, AMZ Slawin…

Index: Zhang, Qingzhi; Hua, Guoxiong; Bhattacharyya, Pravat; Slawin, Alexandra M. Z.; Woollins, J. Derek European Journal of Inorganic Chemistry, 2003 , # 13 p. 2426 - 2437

Full Text: HTML

Citation Number: 10

Abstract

Abstract Two aminomethylphosphane derivatives of adenine 9-(2-{bis [(diphenylphosphanyl) methyl] amino} ethyl) adenine (La) and 9-(3-{bis [(diphenylphosphanyl) methyl] amino} propyl) adenine (Lb) were synthesised. Oxidation of La and Lb with H 2 O 2, elemental sulfur or elemental selenium led to the corresponding oxidized products 4a/b− 6a/b. Both La and Lb behave as didentate ligands towards late ...