Journal of Fluorine Chemistry

Exchange reactions between perfluoro-(2, 4-dimethyl-3-oxa-2, 4-diazapentane) and tris (trifluoromethyl) phosphine,-arsine and-stibine

HG Ang, WS Lien

Index: Ang, H. G.; Lien, W. S. Journal of Fluorine Chemistry, 1978 , vol. 11, p. 419 - 432

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Citation Number: 5

Abstract

Abstract Perfluoro-(2, 4-dimethyl-3-oxa-2, 4-diazapentane) reacts with tris (trifluoromethyl) phosphine and-arsine to afford [(CF 3) 2 N] n M (CF 3) 3-n (M= P, n= 1, 2, and 3; and M= As, n= 1, and 2), tris (trifluoromethyl) hydroxylamine being eliminated in each case. The reactions with tris (trifluoromethyl) stibine, on the other hand, give antimony trifluoride, tris (trifluoromethyl) hydroxylamine and perfluoro-2-azapropene.