Perfluoroalkyl derivatives of nitrogen. Part XXV. The reactions of tristrifluoromethylhydroxylamine and mercuric bistrifluoromethylamide with unsaturated systems

RN Haszeldine, AE Tipping

Index: Haszeldine,R.N.; Tipping,A.E. Journal of the Chemical Society [Section] C: Organic, 1967 , p. 1241 - 1249

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Citation Number: 5

Abstract

Tristrifluoromethylhydroxylamine reacts with perfluorocyclobutene, on irradiation, to give the 1: 1 adduct perfluoro-(1-dimethylamino-2-methoxycyclobutane), and lower yields of other products including perfluoro-(1, 2-bisdimethylaminocyclobutane), perfluoro-(2, 2′- dimethoxybicyclobutyl), and perfluoro-(2-dimethylamino-2′-methoxybicyclobutyl). Reaction with perfluorobut-2-ene is more complex. Perfluoro-2-azapropene gives low yields of the ...