The Synthesis and Chemistry of Fluoroazoalkanes

WJ Chambers, CW Tullock…

Index: Chambers,W.J. et al. Journal of the American Chemical Society, 1962 , vol. 84, p. 2337 - 2343

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Citation Number: 50

Abstract

Fluoroazoalkanes (RrN= NRr) have been synthesized by reactions of lower valent metal fluorides and chlorine or bromine with cyanogen chloride and with carbonitriles of fluorocarbons and chlorocarbons. The fluoroazoalkanes have been found to serve as a source of fluoroalkyl radicals and to participate in various syntheses. Thus, with carbon monoxide they yield Auoroalkyl isocyanates; in Diels-Alder additions with 1, a-dienes they ...

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