Direct one-pot synthesis of terminal olefins and deuterio olefins from carboxylic acid chlorides

J Barluenga, M Yus, JM Concellon…

Index: Barluenga, Jose; Yus, Miguel; Concellon, Jose M.; Bernad, Pablo Journal of Organic Chemistry, 1983 , vol. 48, # 18 p. 3116 - 3118

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Citation Number: 10

Abstract

Recently we have reported a regioselective method to obtain olefins and deuterio olefins from a-chloro carbonyl compounds, Grignard reagents or lithium aluminum hydride or deuteride, and 1ithium. l These results prompted us to use the Nierenstein chloromethylation reaction2 in a one-pot tandem process with the above-described method to obtain terminal olefins and deuterio olefins using carboxylic acid chlorides as starting materials. The ...