Cleavage of the PC bond in the reactions of phosphoryl-substituted CH acids with 1-fluoro-2, 4, 6-trinitrobenzene in the presence of bases

YG Gololobov, IY Krasnova, EV Matveeva…

Index: Gololobov; Krasnova; Matveeva; Petrovskii Russian Chemical Bulletin, 2010 , vol. 59, # 5 p. 1059 - 1060

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Citation Number: 2

Abstract

Formation and cleavage of the P—C bonds in the organophosphorus compounds are of fundamental im portance. In our laboratory, base assisted cleavage of the P—C bond, which occurred smoothly in the reactions of the phosphorus containing CH acids 1 with 1 fluoro 2, 4, 6 trinitrobenzene, was discovered (Scheme 1).