Fluorination of phosphorus (+ 3) derivatives by xenon difluoride

…, SI Zavorin, II Sukhojenko, NV Kuryleva…

Index: Lermontov, S. A.; Popov, A. V.; Zavorin, S. I.; Sukhojenko, I. I.; Kuryleva, N. V.; et al. Journal of Fluorine Chemistry, 1994 , vol. 66, # 3 p. 233 - 236

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Citation Number: 9

Abstract

Abstract Xenon difluoride, XeF 2, effectively fluorinates various phosphorous acid derivatives as well as hydrophosphoryl compounds. Arbuzov rearrangement is followed by i- Bu→ t-Bu isomerization in the case of i-Bu OPF 2.