Decamethylrhenocene,(. eta. 5-C5Me5) 2Re

JA Bandy, FGN Cloke, G Copper, JP Day…

Index: Bandy, Judith A.; Cloke, F. Geoffrey N.; Cooper, Glyn; Day, Jeremy P.; Girling, Reuben B.; et al. Journal of the American Chemical Society, 1988 , vol. 110, # 15 p. 5039 - 5050

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Citation Number: 37

Abstract

Abstract: The synthesis of CP*~ R~ H (Cp*= $-C5Me5) from Re vapor and CSMeSH and its photochemical conversion into CP*~ R~ are described. The X-ray crystal structure of the latter has been determined and shows the molecule to possess the parallel ring, eclipsed, sandwich structure (space group R1/m, a= 8.620 (3), b= 14.593 (5), c= 7.923 (3) A, 2= 2, refinement on 1871 reflections, R,= 0.037). The solid-state magnetic moment reveals ...