Synthesis and characterization of 1, 8, 15, 22-tetraoxa [8.8] paracyclophane-3, 5, 17, 19-tetrayne-10, 25-dicarboxylic acid, a novel water-soluble and donut-shaped …

ET Jarvi, HW Whitlock Jr

Index: Jarvi, E. T.; Whitlock, H. W. Journal of the American Chemical Society, 1980 , vol. 102, # 2 p. 657 - 662

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Citation Number: 40

Abstract

Abstract: Synthesis of the title molecule (1) along with an investigation of its conformation and ability 10 form inclusion-type stacking complexes with aromatic and aliphatic guests is described. It is shown that 1 possesses a geometry with the two aromatic rings well separated by the rigid dioxaoctadiyne spacers. Its perhydro derivative 7 in contrast exists in a collapsed conformation. Complexation of 1 with aromatic guests proceeds not via ...