e.g. Filippa Pettersson or Cancer Res. 75(6) , 1102-12, (2015) or 10.1002/anie.201600521
Iridium-mediated N–H and methyl C–H bond activations in N-(2′, 6′-dimethylphenyl) pyrrole-2-aldimine. Synthesis, characterization and catalytic applications
P Paul, MG Richmond, S Bhattacharya
Index: Paul, Piyali; Richmond, Michael G.; Bhattacharya, Samaresh Journal of Organometallic Chemistry, 2014 , vol. 751, p. 760 - 768
Abstract Reaction of N-(2′, 6′-dimethylphenyl) pyrrole-2-aldimine (L-Me 2) with Ir (PPh 3) 3 Cl in refluxing toluene affords two organometallic complexes (1 and 2), where the imine- ligand (L-Me 2) is coordinated to the metal center, via N–H and methyl C–H activations, as a di-anionic tridentate NNC-donor, along with two triphenylphosphines. In 1 the sixth coordination site is occupied by a hydride, while in 2 by a chloride. In both cases the ...
