The preparation of alkylaryldichlorocyclopropanol phosphates

Q Xi, X Lin, J Chang, Y Ding

Index: Xi, Qi; Lin, Xingji; Chang, Jianhua; Ding, Yixiang Phosphorus, Sulfur and Silicon and the Related Elements, 2003 , vol. 178, # 1 p. 47 - 54

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Abstract

In the present article we report the preparation of alkylaryldichlorocyclopropanol phosphates by the addition of dichlorocarbene to enol phosphates of propiophenone and cyclohexanone with steric hinderance. The stereoselectivity of enol phosphates and the effect of substituents on the carbene addition rate are discussed.