Catalytic oxidation of phenols to p-quinones with the hydrogen peroxide and methyltrioxorhenium (VII) system

W Adam, WA Herrmann, J Lin…

Index: Journal of Organic Chemistry, , vol. 59, # 26 p. 8281 - 8283

Full Text: HTML

Citation Number: 111

Abstract

... Chemistry, University of Wiirzburg, Am Hubland, 0-97074 Wurzburg, Germany, and Institute of Inorganic Chemistry, Technische Universitat ... desirable starting materials for the synthesis of p-benzoquinones, which constitute important oxidations in organic syn- thesis. ... 8282 J. Org. ...

 Related Synthetic Route
2,6-Di-tert-butylphenol Structure

128-39-2

2,6-Di-tert-but...

~66%

2,6-Di-tert-butyl-p-benzoquinone Structure

719-22-2

2,6-Di-tert-but...

3,5-ditert-butyl-4-hydroxycyclohexa-3,5-diene-1,2-dione Structure

21243-82-3

3,5-ditert-buty...

3,5-Di-tert-butylphenol Structure

1138-52-9

3,5-Di-tert-but...

~8%

2,7-Oxepindione,3,5-bis(1,1-dimethylethyl)- Structure

24289-60-9

2,7-Oxepindione...

2,6-Di-tert-butyl-p-benzoquinone Structure

719-22-2

2,6-Di-tert-but...

3,5-ditert-butyl-4-hydroxycyclohexa-3,5-diene-1,2-dione Structure

21243-82-3

3,5-ditert-buty...

2,3,6-Trimethylphenol Structure

2416-94-6

2,3,6-Trimethyl...

~68%

trimethyl-p-benzoquinone Structure

935-92-2

trimethyl-p-ben...

2-hydroxyl-3,5,6,-trimethyl-benzoquinone Structure

2913-43-1

2-hydroxyl-3,5,...

2,3,5-Trimethylphenol Structure

697-82-5

2,3,5-Trimethyl...

~49%

trimethyl-p-benzoquinone Structure

935-92-2

trimethyl-p-ben...

2-hydroxyl-3,5,6,-trimethyl-benzoquinone Structure

2913-43-1

2-hydroxyl-3,5,...

2,5-Dimethylphenol Structure

95-87-4

2,5-Dimethylphenol

~45%

3-hydroxy-2,5-dimethylcyclohexa-2,5-diene-1,4-dione Structure

2913-41-9

3-hydroxy-2,5-d...

2,5-Dimethylquinone Structure

137-18-8

2,5-Dimethylquinone

2-Methyl-1-naphthol Structure

7469-77-4

2-Methyl-1-naphthol

~72%

Phthiocol Structure

483-55-6

Phthiocol

Menadione Structure

58-27-5

Menadione


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