Inorganica Chimica Acta

… chemical vapour deposition (AACVD) of silver films from triorganophosphine adducts of silver carboxylates, including the structure of [Ag (O 2 CC 3 F 7)(PPh 3) 2]

DA Edwards, RM Harker, MF Mahon, KC Molloy

Index: Edwards, Dennis A; Harker, Robert M; Mahon, Mary F; Molloy, Kieran C Inorganica Chimica Acta, 2002 , vol. 328, # 1 p. 134 - 146

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Citation Number: 66

Abstract

Silver carboxylates [Ag (O2CR): R= Me, tBu, 2, 4, 6-Me3C6H2], fluorocarboxlyates [Ag (O2CRf): Rf= C3F7, C6F13, C7F15] and their phosphine adducts [Ag (O2CR)· nPR3′: R= Me, tBu, 2, 4, 6-Me3C6H2, R′= Me, Ph, n= 2; R= Me, R′= Me, n= 3; Ag (O2CRf). 2PPh3, Rf= C3F7, C6F13, C7F15] have been synthesised, characterised spectroscopically and used as precursors in the aerosol-assisted chemical vapour deposition of silver films. All ...