Regioselective ring opening of [(perfluoroalkyl) methyl] oxiranes with N-nucleophiles

…, R Bertani, G Gambaretto, A Berton, R Seraglia

Index: Conte; Maniero; Zaggia; Bertani; Gambaretto; Berton; Seraglia Journal of Fluorine Chemistry, 2005 , vol. 126, # 9-10 p. 1274 - 1280

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Citation Number: 14

Abstract

The reactions of with some primary and secondary aliphatic amines affording selective ring opening at Cβ are reported. The reactions with secondary amines HNR1R2 (R1= R2= Et; R1= But, R2= CH2CH2O (CO) C (CH3) CH2; R1= Et, R2= CH2CH2OH; R1= R2= CH2CH2OH) gave the corresponding C8F17CH2CH (OH) CH2NR1R2 derivatives. For R1= Et, R2= CH2CH2OH; R1= R2= CH2CH2OH, the reactions proceed through the selective ...

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