Journal of the American Chemical Society

α-Alkylaminopyridines and 1, 5-Di-(alkyl-α-pyridylamino)-pentanes

FF Blicke, MU Tsao

Index: Blicke; Tsao Journal of the American Chemical Society, 1946 , vol. 68, p. 905

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Citation Number: 12

Abstract

It has been shown that when a-aniinopyridine or a-acetylarniiiopyridine2 is treated with a lower alkyl halide3 or an alkylene dihalide,* the pyridine compound reacts to a large extent in the tautomeric imine form, and that only a small amount of the a-alkylaminopyridine is produced. However, in spite of the unavoidable formation of N-alkyl-a-pyridoneimines, it has been stated5 that interaction of higher alKyl halides (10-14 carbon atoms) with a- ...