Mechanism of gold (I)-catalyzed rearrangements of acetylenic amine-N-oxides: computational investigations lead to a new mechanism confirmed by experiment

EL Noey, Y Luo, L Zhang, KN Houk

Index: Journal of the American Chemical Society, , vol. 134, # 2 p. 1078 - 1084

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Citation Number: 53

Abstract

... Journal of the ... Soc. , 2012, 134 (2), pp 1078–1084. DOI: 10.1021/ja208860x. Publication Date (Web): December 22, 2011. Copyright © 2011 American Chemical Society. ... such as sulfoxide,(3) nitrone,(4) epoxide,(5) nitro,(6) and amine N-oxide,(7) and recently one of us has ...