. beta.-Electrophilic Additions of Pentaammineosmium (II). eta. 2-Pyrrole Complexes

LM Hodges, J Gonzalez, JI Koontz…

Index: Journal of Organic Chemistry, , vol. 60, # 7 p. 2125 - 2146

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Citation Number: 38

Abstract

... The iminium carbon of both W- and 3H-pyrrolium tautomers is considerably less electrophilic than its organic analogs, but readily undergoes borohydride reduction to form complexes of 3- and 2-pyrrolines ... (2) Jones, RA In The Chemistry ofHeterocyclic Compounds ... 2126 J. Org. ...

Selective α-chlorination of acetylpyrroles

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A mild and facile one-pot synthesis of n-methyl-3-acyl-pyrro...

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