Complexes between N-bromosuccinimide and quaternary ammonium bromides and their role in the addition of bromine to olefins

…, SA Hart, WM Moore, SD Ross, L Eberson

Index: Finkelstein, Manuel; Hart, Shirley A.; Moore, W. Michael; Ross, Sidney D.; Eberson, Lennart Journal of Organic Chemistry, 1986 , vol. 51, # 18 p. 3548 - 3551

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Citation Number: 18

Abstract

SBr[C2HJ4NBr 2: l 126-128 59 SBr[C2H6I4NBr 1: l 103 dec 97 SBr C6H5CH2N (C2H6) 3Br 1: l 109-110 89 nisms.” 13 Our recent work14-18 has demonstrated that both SBr and N- chlorosuccinimide (SC1) can participate in rapid electron-transfer reactions with an appropriate nucleophile, eg, the succinimide anion. With SBr the electron transfer probably occurs in a complex formed from SBr and a quaternary ammonium succinimide16 and ...