Bulletin of the Chemical Society of Japan

Photo-induced alkoxybromination of olefins by N, N'-dibromo-2, 5-piperazinedione.

A Sera, H Yamada, K Itoh

Index: Sera, Akira; Yamada, Hiroshi; Itoh, Kuniaki Bulletin of the Chemical Society of Japan, 1980 , vol. 53, # 1 p. 219 - 221

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Citation Number: 8

Abstract

Irradiation of N, N′-dibronio-2, 5-piperazinedione in dichloromethane in the presence of an alcohol induced alkoxybromination of cyclohexene to give trans-1-bromo-2- alkoxycyclohexane in a good yield. The reaction was thought to proceed through an ionic mechanism.