Hydrogen-bonded oxyhemoglobin models with substituted picket-fence porphyrins: the model compound equivalent of site-directed mutagenesis

GE Wuenschell, C Tetreau, D Lavalette…

Index: Wuenschell, Gerald E.; Tetreau, Catherine; Lavalette, Daniel; Reed, Christopher A. Journal of the American Chemical Society, 1992 , vol. 114, # 9 p. 3346 - 3355

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Citation Number: 71

Abstract

Conclusions Hydrothermal synthesis has been demonstrated to provide an effective method for the synthesis of poloxovanadium clusters incorporating conventional organic ligands. The marked cation dependence of the structures allows the isolation of species with different ligand to metal stoichiometries. The clusters Ia and IIa exhibit the decavanadium core (V10O28) with variable numbers of doubly and triply bridging oxo groups replaced by ...