Bis (1-benzyl-4-aza-1-azoniabicyclo (2.2. 2) octane) Peroxodisulfate: A Mild and Efficient Oxidant for Cleavage of Nitrogen Double Bonds and Oxidation of Alcohols …

AR Hajipour, IM -Baltork, G Kianfar

Index: Hajipour, Abdol Reza; Baltork, Iraj Mohammadpoor; Kianfar, Godaraz Bulletin of the Chemical Society of Japan, 1998 , vol. 71, # 11 p. 2655 - 2659

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Citation Number: 42

Abstract

Bis (1-benzyl-4-aza-1-azoniabicyclo [2.2. 2] octane) peroxodisulfate (1), is readily prepared as an orange solid from commercially available 1, 4-diazabicyclo [2.2. 2] octane and potassium peroxodisulfate. This reagent easily converts hydrazones, semicarbazones, oximes, and alcohols to the corresponding carbonyl compounds with excellent yields.