Synthesis and Characterization of Methoxy (thiocarbonyl) sulfenyl Chloride

AL Schroll, SJ Eastep, G Barany

Index: Schroll, Alayne L.; Eastep, Steven J.; Barany, George Journal of Organic Chemistry, 1990 , vol. 55, # 5 p. 1475 - 1479

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Citation Number: 11

Abstract

(Methoxy (thiocarbony1)) sulfenyl chloride (l), a previously elusive compound, has now been generated by cleavage of methoxy (thiocarbony1) N-methyl-N-phenylamino sulfide (7) with gaseous hydrogen chloride. The sulfenyl chloride 1 had limited stability and was characterized by trapping with 0, O'-dimethyl thiocarbonate or with methanethiol to yield (methoxycarbonyl)(methoxy (thiocarbonyl)) disulfane (8) or (methoxy (thiocarbony1))- ...