Palladium??Catalyzed Diorganozinc Conjugate Additions to Enones: Preparative and Computational Studies

P Lorenzo, JM Aurrecoechea…

Index: Lorenzo, Paula; Aurrecoechea, Jose M.; De Lera, Angel R.; Alvarez, Rosana European Journal of Organic Chemistry, 2013 , # 13 p. 2621 - 2626

Full Text: HTML

Citation Number: 1

Abstract

Abstract The Pd-catalyzed conjugate addition of diorganozinc reagents to α, β-unsaturated carbonyl compounds has been applied to a variety of enone substrates, both cyclic and acyclic, encompassing various combinations of aryl and alkyl substitution, in combination with diorganozinc reagents incorporating alkyl (Me, linear and branched) or Ph groups. While both Pd 0 and Pd II complexes have been found to be competent precatalysts, ...