The Journal of Organic Chemistry

4-Thiazoline-2-thiones. II. Preparation of 4-alkylsulfonylmethyl derivatives

WJ Humphlett, RW Lamon

Index: Humphlett,W.J.; Lamon,R.W. Journal of Organic Chemistry, 1964 , vol. 29, p. 2148 - 2150

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Citation Number: 15

Abstract

A series of 4-alkylsulfonylmethy1 derivatives of 4-through an intermediate product which can be isolated thiazoline-2-thiones has been obtained by reaction of and has been shown to be a substituted 4-hydroxythiammonium dithiocarbamate and 1-alkylsulfonyl-3-a~ olidine-2- thione.~ In a subsequent step, dehydrabromo-2-propanones. This type of synthesis proceeds tion forms a 4-thiazoline ring. Required l-alkylsulfonyl-3-bromo-2-propanones ...