Synthesis, Characterisation and Catalytic Application of Oxidorhenium Complexes Bearing H??Spirophosphorane Ligands

A Skarżyńska, M Siczek…

Index: Skarzynska, Anna; Siczek, Milosz; Sobczak, Jaroslaw M. European Journal of Inorganic Chemistry, 2012 , # 20 p. 3331 - 3341

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Abstract

Abstract The coordination properties of the H-spirophosphorane ligands HP (OCMe 2 CMe 2 O) 2 (L1), HP (OCHMeCHMeO) 2 (L2) and HP (OCH 2 CMe 2 NH) 2 (L3) towards rhenium have been studied, and the complexes cis-[ReOCl 2 {P (OCMe 2 CMe 2 O) OCMe 2 CMe 2 O} pic](1a), cis-and trans-[ReOCl 2 {P (OCMe 2 CMe 2 O) OCMe 2 CMe 2 O} lut](2a and 2b), cis-and trans-[ReOBr 2 {P (OCMe 2 CMe 2 O) OCMe 2 CMe 2 O} PPh 3](3a and 3b),[nBu ...