Intramolecular Binaphthyl Formation from Radical Cations of Tri-1-naphthyl Phosphate and Related Compounds in Photoinduced Electron-Transfer Reactions …

M Nakamura, R Dohno, T Majima

Index: Nakamura, Mitsunobu; Dohno, Reizo; Majima, Tetsuro Chemical Communications, 1997 , # 14 p. 1291 - 1292

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Citation Number: 7

Abstract

The photoinduced electron transfer of tri-1-naphthyl phosphate and related compounds sensitized by 9, 10-dicyanoanthracene (DCA) in acetonitrile produces 1, 1'-binaphthyl and the corresponding biaryl. The quenching rate constant of the DCA fluorescence is calculated