The Journal of Organic Chemistry

Perfluoroalkyl isocyanates: general synthesis by the pyrolysis of disilyl esters of hydroxamic acids

WJ Middleton

Index: Middleton, William J. Journal of Organic Chemistry, 1984 , vol. 49, # 23 p. 4541 - 4543

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Citation Number: 12

Abstract

Table I. Yields and Physical Data for Compounds 1-14 product” method yield,* % [a]*Oe~, deg mp, “C R t 'H NMR' 13C NMRf ... 2 3 4 5 6 7 8 9 10 11' 12 13 14' ... A A B B B B B B C C C C ... 558 68, 17” 80, 16” 33 38 22 26 19 16 82 81 60 79 ... 75.0-78.0 92.5-93.5 9 2.5-94.0 oil oil

~85%

~55%

~57%

The Rotational Spectrum of Trifluoromethyl Isocyanate

[Koput, J.; Stahl, W.; Heineking, N.; Pawelke, G.; Steger, B.; Christen, D. Journal of Molecular Spectroscopy, 1994 , vol. 168, # 2 p. 323 - 332]

The Synthesis and Chemistry of Fluoroazoalkanes

[Chambers,W.J. et al. Journal of the American Chemical Society, 1962 , vol. 84, p. 2337 - 2343]

Fluorocarbon Nitrogen Compounds. VII. 1 The Indirect Fluorin...

[Young,J.A. et al. Journal of the American Chemical Society, 1960 , vol. 82, p. 4553 - 4556]

Perfluorooxazetidines

[Falk,R.A.; Readio,J.D. Journal of Organic Chemistry, 1969 , vol. 34, p. 4088 - 4090]

Raman and infrared spectra, structure, vibrational assignmen...

[Durig, J. R.; Guirgis, G. A.; Eltayeb, S. Journal of Molecular Structure, 1994 , vol. 324, p. 93 - 106]