e.g. Filippa Pettersson or Cancer Res. 75(6) , 1102-12, (2015) or 10.1002/anie.201600521
1, 5-Asymmetric induction of chirality: diastereoselective addition of organoaluminium reagents and allylstannanes into aldehyde groups in the side-chain of π- …
SV Ley, LR Cox
Index: Ley, Steven V.; Burckhardt, Svenja; Cox, Liam R.; Meek, Graham Journal of the Chemical Society - Perkin Transactions 1, 1997 , # 22 p. 3327 - 3337
π-Allyltricarbonyliron lactone complex 5, bearing an aldehyde group in the side-chain, can be easily prepared from commercially available (2, 4 [][])-ethyl hexadienoate and reacts with organoaluminium and allylstannane nucleophiles to afford secondary alcohols. In analogy with the corresponding ketone-substituted compl
