Combined deuterium nuclear magnetic resonance and mass-spectrometric studies of the exchange reactions of ketones over supported metal catalysts

CG Pope, C Kemball, GS McDougall

Index: Pope, Christopher; Kemball, Charles; McDougall, Gordon S. Journal of the Chemical Society, Faraday Transactions, 1990 , vol. 86, # 4 p. 747 - 752

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Citation Number: 3

Abstract

Deuterium NMR spectroscopy has been used in conjunction with mass spectrometry to study the exchange reaction of the ketones acetone, butan-2-one and cyclopentanone over a variety of supported metal catalysts. In many of the experiments simple, random, stepwise exchange was prevalent. However, in certain instances multiple exchange occurred. For butan-2-one and cyclopentanone this multiple exchange was essentially limited to the ...