Study of the alkylation of chlorosilanes. Part II. Synthesis of (fluoroalkyl) chlorosilanes and tetra (fluoroalkyl) silanes via hydrosilylation

B Boutevin, F Guida-Pietrasanta, A Ratsimihety…

Index: Boutevin, B.; Guida-Pietrasanta, F.; Ratsimihety, A.; Caporiccio, G. Journal of Fluorine Chemistry, 1994 , vol. 68, # 1 p. 71 - 78

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Citation Number: 18

Abstract

Abstract The hydrosilylation of various fluorinated olefins and of a diene with different chlorosilanes and with a tri (fluoroalkyl) silane, in the presence of a peroxide or a Pt catalyst, is reported. The reactivity is influenced considerably by the structure of the silane and of the fluorinated olefin. The following (fluoroalkyl) chlorosilanes and (fluoroalkyl)-α, ω- chlorodisilanes are described; C 6 F 13 (CH 2) n, SiR 1 R 2 Cl where n= 2 or 3 and (ClR 1 ...